全文获取类型
收费全文 | 12257篇 |
免费 | 2044篇 |
国内免费 | 1735篇 |
专业分类
化学 | 8985篇 |
晶体学 | 151篇 |
力学 | 736篇 |
综合类 | 127篇 |
数学 | 1596篇 |
物理学 | 4441篇 |
出版年
2024年 | 12篇 |
2023年 | 173篇 |
2022年 | 263篇 |
2021年 | 350篇 |
2020年 | 427篇 |
2019年 | 442篇 |
2018年 | 390篇 |
2017年 | 380篇 |
2016年 | 543篇 |
2015年 | 567篇 |
2014年 | 710篇 |
2013年 | 895篇 |
2012年 | 1065篇 |
2011年 | 1213篇 |
2010年 | 873篇 |
2009年 | 891篇 |
2008年 | 1009篇 |
2007年 | 868篇 |
2006年 | 793篇 |
2005年 | 604篇 |
2004年 | 456篇 |
2003年 | 362篇 |
2002年 | 382篇 |
2001年 | 336篇 |
2000年 | 301篇 |
1999年 | 253篇 |
1998年 | 194篇 |
1997年 | 170篇 |
1996年 | 196篇 |
1995年 | 170篇 |
1994年 | 107篇 |
1993年 | 104篇 |
1992年 | 86篇 |
1991年 | 84篇 |
1990年 | 65篇 |
1989年 | 65篇 |
1988年 | 39篇 |
1987年 | 38篇 |
1986年 | 34篇 |
1985年 | 25篇 |
1984年 | 19篇 |
1983年 | 21篇 |
1982年 | 14篇 |
1981年 | 10篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1974年 | 4篇 |
1972年 | 4篇 |
1971年 | 3篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
81.
Low‐temperature headspace‐trap gas chromatography with mass spectrometry for the determination of trace volatile compounds from the fruit of Lycium barbarum L. 下载免费PDF全文
The total saccharides content of Lycium barbarum L. is very high, and a high temperature would result in saccharide decomposition and the emergence of a large amount of water. Moreover, the volatile compounds from the fruit of L. barbarum L. are rather low in concentration. Hence, it is difficult for a conventional headspace method to study the volatile compounds from the fruit of L. barbarum L. Since headspace‐trap gas chromatography with mass spectrometry is an excellent method for trace analysis, a headspace‐trap gas chromatography with mass spectrometry method based on low‐temperature (30°C) enrichment and multiple headspace extraction was developed to explore the volatile compounds from the fruit of L. barbarum L. The headspace of the sample was extracted in 17 cycles at 30°C. Each time, the compounds extracted were concentrated in the trap (Tenax TA and Tenax GR, 1:1). Finally, all the volatile compounds were delivered into the gas chromatograph after thermal desorption. With the method described above, a total of 57 compounds were identified. The identification was completed by mass spectral search, retention index, and accurate mass measurement. 相似文献
82.
One Step Preparation of Reduced Graphene Oxide/Pd–Fe3O4@Polypyrrole Composites and Their Application in Catalysis 下载免费PDF全文
Dr. Tongjie Yao Hao Wang Quan Zuo Dr. Jie Wu Dr. Xiao Zhang Dr. Fang Cui Dr. Tieyu Cui 《化学:亚洲杂志》2015,10(9):1940-1947
The simple preparation of catalysts with superior catalytic activity and good reusability is highly desirable. Herein, we report a novel strategy to construct reduced graphene oxide (rGO)/Pd–Fe3O4@polypyrrole (PPy) catalysts with Pd and Fe3O4 nanoparticles anchored on a rGO nanosheet surface and wrapped in a PPy shell. The synthesis and assembly of both the Pd and Fe3O4 nanoparticles, the preparation of the PPy layer, and the reduction of graphene oxide nanosheets were finished in one step. In the system, the PPy layer not only prevented aggregation of Pd and Fe3O4 nanoparticles, but also generated a synergistic effect with precursor Pd2+ ions, which led to a high dispersity of as‐prepared Pd nanoparticles. Although the procedure was simplified to one step, the catalytic activity and reusability were not sacrificed. In the reduction of 4‐nitrophenol, their catalytic performance was better than that in recent reports. Moreover, the catalysts showed good reusability owing to their magnetic properties. 相似文献
83.
Lei Wang Man Zhang Ying‐Ying Jin Qing Lu Qi Fang 《Acta Crystallographica. Section C, Structural Chemistry》2015,71(1):69-74
Three 1‐phenylindolin‐2‐one derivatives, namely 1‐phenylindolin‐2‐one, C14H11NO, (I), 5‐bromo‐1‐phenylindolin‐2‐one, C14H10BrNO, (II), and 5‐iodo‐1‐phenylindolin‐2‐one, C14H10INO, (III), have been synthesized and their structures determined. Compounds (I) and (II) crystallized in the centrosymmetric space groups Pbca and P21/c, respectively, while compound (III) crystallized in the polar space group Aea2. Density functional theory (DFT) calculations show that the molecular dipole moment gradually decreases in the order (I) > (II) > (III). The relatively smaller dipole moment of (III) and the larger non‐electrostatic intermolecular interactions may be the main reasons for the noncentrosymmetric and polar structure of (III). 相似文献
84.
In this paper, we establish the existence of three weak solutions for quasilinear elliptic equations in an Orlicz-Sobolev space via an abstract result recently obtained by Ricceri in [13]. 相似文献
85.
Blow‐up phenomena for a semilinear parabolic equation with weighted inner absorption under nonlinear boundary flux 下载免费PDF全文
Blow‐up phenomena for a nonlinear divergence form parabolic equation with weighted inner absorption term are investigated under nonlinear boundary flux in a bounded star‐shaped region. We assume some conditions on weight function and nonlinearities to guarantee that the solution exists globally or blows up at finite time. Moreover, by virtue of the modified differential inequality, upper and lower bounds for the blow‐up time of the solution are derived in higher dimensional spaces. Three examples are presented to illustrate applications of our results. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
86.
In this paper, we are interested in exploring the dynamic causal relationships among two sets of three variables in different quarters. One set is futures sugar closing price in Zhengzhou futures exchange market (ZC), spot sugar price in Zhengzhou (ZS) and futures sugar closing price in New York futures exchange market(NC) and the other includes futures sugar opening price in Zhengzhou (ZO), ZS and NC. For each quarter, we first use Bayesian model selection to obtain the optimal causal graph with the highest BD scores and then use Bayesian model averaging approach to explore the causal relationship between every two variables. From the real data analysis, the two conclusions almost coincide, which shows that the two methods are practical. 相似文献
87.
Guangwu Wang Boling Guo Shaomei Fang 《Mathematical Methods in the Applied Sciences》2017,40(14):5262-5272
In this paper, we will firstly extend the results about Jiu, Wang, and Xin (JDE, 2015, 259, 2981–3003). We prove that any smooth solution of compressible fluid will blow up without any restriction about the specific heat ratio γ. Then we prove the blow‐up of smooth solution of compressible Navier–Stokes equations in half space with Navier‐slip boundary. The main ideal is constructing the differential inequality. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
88.
Qing-yao Wang Jia-qi Fang Lu-lu Deng Xiao-jiang Hao Shu-zhen Mu 《Chemistry Central journal》2017,11(1):138
The regioselective demethoxylation and dehalogenation of dihalogenated dibenzocyclooctadiene lignans derivatives were realized in a one-step reaction with excellent yields in the sodium and t-butanol reaction system. 相似文献
89.
本文构建了一种基于3-苯丙噻唑基-2-羟基-5-甲基苯甲醛的荧光探针用于检测铝离子。该荧光探针能够灵敏、高选择性地检测铝离子,并显示出颜色和强烈的荧光变化双重响应。研究结果表明,该探针对铝离子表现出非常好的荧光增强效果,检测过程中其它金属离子不会对检测结果产生明显的干扰。其比率荧光强度(I490/I567)与铝离子的浓度(0~20μmol/L)之间具有良好的线性关系,检测限低至0.5μmol/L。由于具有高效的选择性,该探针可以用于检测污染河水中的铝离子含量。 相似文献
90.
Compact molecular packing with short π-π stacking and large π-overlap in organic semiconductors is desirable for efficient charge transport and high carrier mobility.Thus charge transport anisotropy along different directions is commonly observed in organic semiconductors.Interestingly,in this article,we found that comparable charge transport property were achieved based on the single crystals of a bis-fused tetrathiafulvalene derivative(EM-TTP) compound along two interaction directions,that is,the multiple strong S…S intermolecular interactions and the π-π stacking direction,with the measured electrical conductivity and hole mobility of 0.4 S cm~(-1),0.94 cm~2 V~(-1) s~(-1) and 0.2 S cm~(-1),0.65 cm2 V~(-1) s~(-1),respectively.This finding provides us a new molecular design concept for developing novel organic semiconductors with isotropic charge transport property through the synergistic effect of multiple intermolecular interactions(such as S…S interactions) and π-π stacking. 相似文献